The synthesis and electronic absorption spectra of 3-phenyl-3(4-pyrrolidino-2-substituted phenyl)-3H-naphtho[2,1-b]pyrans:: further exploration of the ortho substituent effect

The synthesis and electronic absorption spectra of 3-phenyl-3(4-pyrrolidino-2-substituted phenyl)-3H-naphtho[2,1-b]pyrans:: further exploration of the ortho substituent effect
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DOI:
10.1016/j.tet.2005.09.143
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发表时间:
2006-01-23
期刊:
影响因子:
2.1
通讯作者:
Instone, AC
Instone, AC
中科院分区:
化学3区
文献类型:
--
作者:
Gabbutt, CD;Heron, BM;Instone, AC

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将取代基引入3,3-二芳基-3 H-萘并[2,1-B]吡喃的3-(4-吡咯烷基苯基)环的空间要求高的2-位,导致产生额外的短波长吸收带,导致有机光致变色物,其表现为橙子和红色的暗色调。(c)2005爱思唯尔有限公司保留所有权利。
Introduction of a substituent into a sterically demanding 2-position of a 3-(4-pyrrolidinophenyl) ring of a 3,3-diaryl-3H-naphtho[2,1-b]pyran results in the generation of an additional short wavelength absorption band leading to organic photochromes that appear as dull shades of orange and red. (c) 2005 Elsevier Ltd. All rights reserved.