Rare Earth Starting Materials and Methodologies for Synthetic Chemistry.

Rare Earth Starting Materials and Methodologies for Synthetic Chemistry.
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DOI:
10.1021/acs.chemrev.1c00842
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发表时间:
2022-03-23
期刊:
影响因子:
62.1
通讯作者:
Ortu, Fabrizio
Ortu, Fabrizio
中科院分区:
化学1区
文献类型:
--
作者:
Ortu, Fabrizio

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用于合成的稀土(RE)起始材料的数量是惊人的,从简单的二元金属卤化物盐到硼氢化物和“设计试剂”,如烷基和有机铝酸盐配合物。本文整理了稀土合成化学中最重要的起始材料,包括其制备及其在现代合成方法中的应用的基本信息。本综述按起始材料类别和辅助配体(即作为合成前体的金属、卤化物、硼氢化物、氮供体、氧供体、三氟酸盐和有机金属试剂)进行了划分,并在每个部分中讨论了相关的合成方法和应用。
The number of rare earth (RE) starting materials used in synthesis is staggering, ranging from simple binary metal-halide salts to borohydrides and “designer reagents” such as alkyl and organoaluminate complexes. This review collates the most important starting materials used in RE synthetic chemistry, including essential information on their preparations and uses in modern synthetic methodologies. The review is divided by starting material category and supporting ligands (i.e., metals as synthetic precursors, halides, borohydrides, nitrogen donors, oxygen donors, triflates, and organometallic reagents), and in each section relevant synthetic methodologies and applications are discussed.
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发表时间: 1996-08-14
影响因子: 15
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