Polarization, donor-acceptor interactions, and covalent contributions in weak interactions: a clarification

Polarization, donor-acceptor interactions, and covalent contributions in weak interactions: a clarification
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DOI:
10.1007/s00894-017-3473-y
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发表时间:
2017-10-01
影响因子:
2.2
通讯作者:
Clark, Timothy
Clark, Timothy
中科院分区:
化学4区
文献类型:
--
作者:
Clark, Timothy

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从弱相互作用的角度讨论了极化(感应)、电荷转移和共价键贡献的概念。它们被证明是同一现象的不同化身,因此用极化来描述它们是最一致的,因为它是三者中唯一真实的、可测量的和唯一定义的量。色散作为费曼描述中偏振的一种形式被讨论。描述了模型计算。
The concepts of polarization (induction), charge transfer and covalent bonding contributions are discussed in terms of weak interactions. They are shown to be different incarnations of the same phenomenon, so that using polarization to describe them is most consistent as it is the only real, measurable and uniquely defined quantity of the three. Dispersion is discussed as a form of polarization within the Feynman description. Model calculations are described.