Flame retardant challenges for textiles and fibres: New chemistry versus innovatory solutions
Flame retardant challenges for textiles and fibres: New chemistry versus innovatory solutions
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DOI：
10.1016/j.polymdegradstab.2010.03.036
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发表时间：
2011-03-01
影响因子：
5.9
通讯作者：
Horrocks, A. Richard
中科院分区：
文献类型：
--
作者：
Horrocks, A. Richard
近50年前，1950-1960年期间见证了化学的发展，这些化学是当今大多数成功和持久的纤维和纺织品阻燃处理的基础。在今天的市场上，在环境可持续性、化学毒理学可接受性、性能和成本方面更为关键，其中许多都受到质疑。“是否有潜在的替代品来取代现有的、耐用的基于甲醛的阻燃剂，如基于四（羟甲基）鏻盐和烷基取代的阻燃剂。纤维素纺织品的N-羟甲基膦酰丙酰胺化学？“是一个经常被问到的问题。“我们能生产成炭聚酯阻燃剂吗？我们真的能生产出有效的无卤素涂料和背面涂层纺织品的替代品吗？这些问题最初是作为对二十世纪后半叶进行的研究的历史回顾来解决的，二十世纪后半叶是大多数目前可用的商业化阻燃纤维和纺织品的基础。研究报告在第一个十年的21世纪，主要解决当前的问题，环境的可持续性和替代阻燃剂的解决方案，需要增加成炭特性的合成纤维和当前的兴趣在纳米技术进行了严格的讨论。微和纳米纤维表面处理和它们的发展使用的技术，如等离子体技术的可能作用也进行了审查。(C)2010爱思唯尔有限公司版权所有。
Almost 50 years ago, the 1950-1960 period witnessed the development of the chemistry underlying most of today's successful and durable flame retardant treatments for fibres and textiles. In today's more critical markets in terms of environmental sustainability, chemical toxicological acceptability, performance and cost, many of these are now being questioned. "Are there potential replacements for established, durable formaldehyde-based flame retardants such as those based on tetrakis (hydroxylmethyl) phosphonium salt and alkyl-substituted. N-methylol phosphonopropionamide chemistries for cellulosic textiles?" is an often-asked question. "Can we produce char-forming polyester flame retardants?" and "Can we really produce effective halogen-free replacements for coatings and back-coated textiles?" are others.These questions are addressed initially as a historical review of research undertaken in the second half of the twentieth century which is the basis of most currently available, commercialised flame retardant fibres and textiles. Research reported during the first decade of the twenty first century and which primarily addresses the current issues of environmental sustainability and the search for alternative flame retardant solutions, the need to increase char-forming character in synthetic fibres and the current interest in nanotechnology is critically discussed. The possible roles of micro- and nano-surface treatments of fibre surfaces and their development using techniques such as plasma technology are also reviewed. (C) 2010 Elsevier Ltd. All rights reserved.