Direct fabrication and morphology of metallic micropatterns by pulsed jet nanoelectrospraying of silver nano-ink
Direct fabrication and morphology of metallic micropatterns by pulsed jet nanoelectrospraying of silver nano-ink
复制标题
脉冲喷射纳米电喷雾银纳米墨水直接制备金属微图案并形成形貌
DOI：
10.1007/s11998-011-9370-x
复制
发表时间：
2012
影响因子：
2.3
通讯作者：
J. Stark
中科院分区：
文献类型：
--
作者：
Ke Wang;J. Stark
将脉冲喷射纳米电喷涂技术应用于银微图形的直接制备。商品有机银纳米墨水的沉积是在完全电压控制的方式下进行的，电压脉冲的范围从550到800伏，持续时间可变。采用15μm喷嘴，在喷涂距离为2 5 0μm的硅片上局部自由形成了尺寸为10 0μm的图形.X射线能谱分析证实，在2 2 0℃热处理后，所有图形中都形成了金属银.观察到银膜的尺寸和微观结构的演变强烈地依赖于沉积体积和衬底表面的物质流动.在锥形喷射模式下，沉积体积与脉冲宽度在外加电压范围内呈良好的线性关系，表现出按需滴入的能力。通过拟合，沉积体积速率估计在0.38-0.59pl/ms范围内，并随外加电压的增加而增大。
A pulsed jet nanoelectrospray technique was applied to direct fabrication of silver micropatterns. The deposition of a commercial organic silver nano-ink was performed in a fully voltage-controlled fashion by voltage pulses ranging from 550 to 800 V with variable durations. By using 15 μm nozzles, patterns with 100-μm-sized features were locally freeformed on a silicon substrate with a spraying distance of 250 μm. An energy-dispersive X-ray spectrum confirmed metallic silver was developed in all the patterns after heat treatment at 220°C. The size and microstructural evolution of silver films was observed to strongly depend on the deposition volume and material flow over substrate surface. A good linear relationship between the deposition volume and pulse duration was exhibited over the applied voltage range in the cone-jet mode, demonstrating a drop-on-demand capability. By fitting, the deposition volume rate was estimated to be in the range of 0.38–0.59 pL/ms and was shown to increase with the applied voltage.
DOI：
10.1007/s10854-008-9843-6
发表时间：
2009-01
期刊：
Journal of Materials Science: Materials in Electronics
影响因子：
--
作者：
Ke Wang;M. Paine;J. Stark
通讯作者：
Ke Wang;M. Paine;J. Stark