Visible-light-promoted 3,5-dimethoxyphenyl glycoside activation and glycosylation

Visible-light-promoted 3,5-dimethoxyphenyl glycoside activation and glycosylation
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可见光促进的 3,5-二甲氧基苯基糖苷活化和糖基化

DOI:
10.1039/d1cc04473g
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发表时间:
2021-09-23
影响因子:
4.9
通讯作者:
Ye, Xin-Shan
Ye, Xin-Shan
中科院分区:
化学2区
文献类型:
--
作者:
Cao, Yafei;Zhou, Minmin;Ye, Xin-Shan

文献摘要

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开发了一种以3,5-二甲氧基苯基糖苷为供体的可见光促进的糖基化新方法。该方案使用多种 O-亲核试剂和核碱基作为糖基受体,以中等至优异的产率提供 O-糖苷和 N-糖苷。
A new glycosylation method promoted by visible light with 3,5-dimethoxyphenyl glycoside as the donor was developed. This protocol delivers both O-glycosides and N-glycosides in moderate to excellent yields using a wide range of O-nucleophiles and nucleobases as the glycosyl acceptors.