Constitutionally adaptive crown ether-based macrocyclic bolaamphiphile with redox-responsive switching of lower critical solution temperature behaviors
Constitutionally adaptive crown ether-based macrocyclic bolaamphiphile with redox-responsive switching of lower critical solution temperature behaviors
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DOI：
10.1016/j.cclet.2021.05.058
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发表时间：
2021-06
影响因子：
9.1
通讯作者：
Qiang-guo Xu;Z. Cui;J. Yao;Bo Li;Ping Lv;Xin Shen;Zhuo Yu;Yan Ge;Zhenhui Qi
中科院分区：
文献类型：
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作者：
Qiang-guo Xu;Z. Cui;J. Yao;Bo Li;Ping Lv;Xin Shen;Zhuo Yu;Yan Ge;Zhenhui Qi
含硒冠醚（CE）的结构自适应化学提供了一个新的平台，用于通过共价键以有效和简单的方式控制/切换bola两亲物骨架在水中的水合作用。大环bola两亲物（C7 SeBola和C7 SeOBola之间的转换）在氧化还原环境的适应性行为被认为是一个决定性因素。
Constitutionally adaptive chemistry of selenium-containing crown ethers (CEs) offers a new platform for controlling/switching the hydration of bolaamphiphile skeletons in water in an effective and simple manner by the virtue of covalent bonding. The adaptive behaviour of the macrocyclic bolaamphiphiles (transformations between C7SeBola and C7SeOBola) in response to redox environment was found to be a decisive factor.