Chemical Synthesis Using Highly Reactive Metals
Chemical Synthesis Using Highly Reactive Metals
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使用高活性金属的化学合成
DOI：
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发表时间：
2016
期刊：
影响因子：
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通讯作者：
R. Rieke
中科院分区：
文献类型：
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作者：
R. Rieke
产品描述：多年来，金属化学已经从基本的起源和标准活化转变为合成化学家使用，制备和应用金属的各种方法选择。20世纪70年代出现了一个重大突破，引入了Rieke金属，Rieke金属是具有高表面积和缺乏表面氧化物的高活性金属粉末。由Rieke金属的创造者撰写，对化学反应方法和效率有价值，使用高反应性金属的化学合成是一本开创性的书，涉及有机和无机化学的重要方面。作者讨论了高活性金属和有机金属试剂的合成方法、制备步骤、化学反应和应用。它涵盖了化学家使用创新技术处理、制备和应用Rieke高活性金属所需的所有信息。开篇章节提供了关于性质和一般制备方法的全面介绍，随后的章节强调了不同的金属，并提供了分步指导，实验描述和适用的化学方程式。总的来说，这本书提出了更安全、更有效的合成、制备和活化的方法。此外，它还具有化学工业的新应用，包括塑料电子，聚合物，光电子和有机发光器件。依靠这本书的化学家将找到一个有价值的资源，研究和发展：新一代的化学，超越了金属和活化的标准使用提供了指导方针和细节处理金属，包括锌，镁，铜，铟，镍，锰，钙，钡，铁，钯，铂，铀，钍，铝，钴，和铬使用独特的方法来突出的方法和技术，使化学合成和活化的里克金属更安全和有效的讨论新的应用和特殊的主题，如高活性金属的半导体聚合物，塑料电子，光化学和Reformatsky试剂和新型有机金属试剂
Description: Metal chemistry has transformed throughout the years from basic origins and standard activation to providing a variety of methodological options for synthetic chemists to use, prepare, and apply metals. A significant breakthrough occurred the 1970 s, with the introduction of Rieke metals, which are highly reactive metal powders that have a high surface area and lack surface oxides. Written by the creator of Rieke metals, valuable for chemical reaction methods and efficiency, Chemical Synthesis Using Highly Reactive Metals is a groundbreaking book addressing a significant aspect of organic and inorganic chemistry. The author discusses synthetic methods, preparation procedures, chemical reactions, and applications for highly reactive metals and organometallic reagents. It covers all the information that a chemist needs in order to handle, prepare, and apply Rieke highly reactive metals with innovative techniques. The opening chapters provide a comprehensive introduction about properties and general methods of preparation and subsequent ones highlight different metals with step–by–step guidance, experimental descriptions, and applicable chemical equations. Overall, the book presents methods for more safe and efficient synthesis, preparation, and activation. In addition, it features novel applications for chemical industries including plastic electronics, polymers, photovoltaics, and organic light–emitting devices. Chemists relying on this book will find a valuable resource for research and development that: Addresses a new generation of chemistry that goes beyond the standard use of metals and activation Provides guidelines and details for handling metals including zinc, magnesium, copper, indium, nickel, manganese, calcium, barium, iron, palladium, platinum, uranium, thorium, aluminum, cobalt, and chromium Uses a unique approach to highlight methods and techniques that make chemical synthesis and activation of Rieke metals more safe and efficient Discusses novel applications and special topics, such as highly reactive metals for semiconducting polymers, plastic electronics, photovoltaics, and the Reformatsky reagent and novel organometallic reagents