A steep one-step [HS-HS] to [LS-LS] spin transition in a 4,4'-bipyridine linked one-dimensional coordination polymer constructed from a pyrazolato bridged Fe(II) dimer.
A steep one-step [HS-HS] to [LS-LS] spin transition in a 4,4'-bipyridine linked one-dimensional coordination polymer constructed from a pyrazolato bridged Fe(II) dimer.
复制标题
DOI：
10.1039/b512266j
复制
发表时间：
2006-12
影响因子：
4.9
通讯作者：
Ko Yoneda;K. Adachi;S. Hayami;Y. Maeda;M. Katada;A. Fuyuhiro;S. Kawata;S. Kaizaki
中科院分区：
文献类型：
--
作者：
Ko Yoneda;K. Adachi;S. Hayami;Y. Maeda;M. Katada;A. Fuyuhiro;S. Kawata;S. Kaizaki
通过变温磁化率、X射线晶体学、穆斯堡尔谱和拉曼谱研究了一种新的双核配合物一维配位聚合物[[Fe（II）2（NCS）2（mu-bpypz）2]（micro-4，4 '-bpy）].MeOH从[HS-HS]到[LS-LS]的自旋转变.
The variable temperature magnetic susceptibility, X-ray crystallography, and Mössbauer and Raman spectra of a new dinuclear complex-based one-dimensional coordination polymer [[Fe(II)2(NCS)2(mu-bpypz)2](micro-4,4'-bpy)].MeOH demonstrated a steep one-step [HS-HS] to [LS-LS] spin transition.