Polytriazoles as copper(I)-stabilizing ligands in catalysis
Polytriazoles as copper(I)-stabilizing ligands in catalysis
复制标题
聚三唑作为催化中的铜(I)稳定配体
DOI：
10.1021/ol0493094
复制
发表时间：
2004-08-19
期刊：
影响因子：
5.2
通讯作者：
Fokin, VV
中科院分区：
文献类型：
--
作者：
Chan, TR;Hilgraf, R;Fokin, VV
聚三唑胺是通过铜(I)催化叠氮化物和炔烃的连接合成的。 C-3-对称衍生物 TBTA 被证明是铜 (I) 的强大稳定配体，可保护其免受氧化和歧化，同时增强其催化活性。
Polytriazolylamines were synthesized by the copper(I)-catalyzed ligation of azides and alkynes. The C-3-symmetric derivative, TBTA, was shown to be a powerful stabilizing ligand for copper(I), protecting it from oxidation and disproportionation, while enhancing its catalytic activity.