Controllable Synthesis of Shuttle-Shaped Ceria and Its Catalytic Properties for CO Oxidation

Controllable Synthesis of Shuttle-Shaped Ceria and Its Catalytic Properties for CO Oxidation
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DOI:
10.1002/ejic.200900362
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发表时间:
2009-09-01
影响因子:
2.3
通讯作者:
Chen, Liquan
Chen, Liquan
中科院分区:
化学3区
文献类型:
--
作者:
Sun, Chunwen;Chen, Liquan

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通过表面活性剂十八胺和尿素辅助的溶剂热过程,以高产率获得了梭状二氧化铈。采用粉末X射线衍射(XRD)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)对晶体结构和形貌进行了表征。初步催化测量表明,梭形CeO2表现出增强的CO氧化活性,这可能归因于其较高的孔隙率和更多的氧空位。 ((C) Wiley-VCH Verlag GmbH & Co. KGaA,69451 魏因海姆,德国,2009 年)
Shuttle-shaped ceria was obtained in a high yield via a surfactant octadecylamine and urea assisted solvothermal process. The crystalline structure and morphology were characterized with powder X-ray diffraction (XRD), scanning electron microscope (SEM), and transmission electron microscope (TEM). Preliminary catalytic measurement shows that the shuttle-shaped CeO2 exhibits an enhanced activity for CO oxidation, which may be attributed to its higher porosity and more oxygen vacancies. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)