Luminescence of Systems Containing Hydroxyl Ion
Luminescence of Systems Containing Hydroxyl Ion
复制标题
含有羟基离子的体系的发光
DOI：
10.1063/1.1673503
复制
发表时间：
1970
期刊：
影响因子：
--
通讯作者：
S. McGlynn
中科院分区：
文献类型：
--
作者：
H. J. Maria;S. McGlynn
在相应的氢氧化碱掺杂的卤化物单晶中观察到荧光，并将其归因于A 2Σ+→X 2Π光产生的羟基自由基的发射。含有氢氧根离子的体系在λ ~ 400 μ处也有磷光，这是由于OH自由基的4Σ−→X 2Π发射所致。本文定性地讨论了含OH -离子体系中的光过程，以及含某些盐和酸的水体系中的光过程。
A fluorescence of alkali halide single crystals doped with the corresponding alkali hydroxide has been observed and is attributed to the A 2Σ+ → X 2Π emission of a photoproduced hydroxyl radical. A phosphorescence of systems containing the hydroxide ion has also been noted at λ ∼ 400 mμ and is attributed to a 4Σ− → X 2Π emission of the OH radical. Photoprocesses in systems containing the OH− ion, as well as in aqueous systems containing certain salts and acids, are discussed in a qualitative way.