Two-Dimensional Lanthanide-Containing Coordination Frameworks: Structure, Magnetic and Luminescence Properties
Two-Dimensional Lanthanide-Containing Coordination Frameworks: Structure, Magnetic and Luminescence Properties
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DOI：
10.1002/zaac.200900300
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发表时间：
2010-03
期刊：
影响因子：
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通讯作者：
Ting Gao;Guangming Li;Pengfei Yan;J. Zhang;Wenbin Sun;M. Suda;Y. Einaga
中科院分区：
文献类型：
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作者：
Ting Gao;Guangming Li;Pengfei Yan;J. Zhang;Wenbin Sun;M. Suda;Y. Einaga
两种含镧的二维配位聚合物[Ln(H2salen)1.5(NO3)3]n [H2salen = n, n ' -乙烯双（水杨基二亚胺）]；Ln = Gd (1), Dy(2)]，采用自组装法制备。研究了金属配合物的分子磁性和发光特性。配合物1在自旋载流子之间表现出反铁磁相互作用。配合物2发出H2salen配体发光。
Two lanthanide-containing 2D coordination polymers, [Ln(H2salen)1.5(NO3)3]n [H2salen = N,N′- ethylenebis(salicylideneimine); Ln = Gd (1), Dy (2)], have been prepared by self-assembly method. The molecular magnetism and luminescence of the metal complexes had been studied. Complex 1 exhibits antiferromagnetic interaction between spin carriers. Complex 2 emits the H2salen ligand luminescence.