Remarkable switching behavior of bimodally stimuli-responsive photochromic dithienylethenes with redox-active organometallic attachments.

Remarkable switching behavior of bimodally stimuli-responsive photochromic dithienylethenes with redox-active organometallic attachments.
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DOI:
10.1039/b809318k
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发表时间:
2008-11
影响因子:
4.9
通讯作者:
K. Motoyama;T. Koike;M. Akita
K. Motoyama;T. Koike;M. Akita
中科院分区:
化学2区
文献类型:
--
作者:
K. Motoyama;T. Koike;M. Akita

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具有氧化还原活性的M(eta(5)-C(5)H(5))L(2)型连接物(M = Fe,Ru; L = CO,PR(3))的有机二噻吩基乙烯表现出双峰刺激响应、光致和伪电致变色行为,其显著的开关因子[K(C)(闭合)/K(C)(打开)]高达5.4 × 10(3)。
Organometallic dithienylethenes with the redox-active M(eta(5)-C(5)H(5))L(2)-type attachments (M = Fe, Ru; L = CO, PR(3)) exhibit bimodally stimuli-responsive, photo- and pseudo-electrochromic behavior with the remarkable switching factors [K(C)(closed)/K(C)(open)] up to 5.4 x 10(3).