THE INFLUENCE OF THE METAL ON THE KINETICS OF OUTER SPHERE REDOX REACTIONS
THE INFLUENCE OF THE METAL ON THE KINETICS OF OUTER SPHERE REDOX REACTIONS
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DOI：
10.1002/bbpc.19850890212
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发表时间：
1985-01-01
期刊：
影响因子：
--
通讯作者：
SCHULTZE, JW
中科院分区：
文献类型：
--
作者：
IWASITA, T;SCHMICKLER, W;SCHULTZE, JW
在六种不同的金属电极上测量了外球氧化还原对[Ru(NH3)6]2+/3+的动力学参数。反应速率与底物无关。讨论了这些结果对电子转移理论的意义，并概述了绝热电子转移反应的新模型。
The kinetic parameters of the outer sphere redox couple [Ru(NH3)6]2+/3+were measured on six different metal electrodes. The reaction rate is independent of the substrate. The significance of these results for the electron transfer theory is discussed, and a new model for adiabatic electron transfer reactions is outlined.