Palladium-catalyzed oxime assisted intramolecular dioxygenation of alkenes with 1 atm of air as the sole oxidant.
Palladium-catalyzed oxime assisted intramolecular dioxygenation of alkenes with 1 atm of air as the sole oxidant.
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DOI：
10.1021/ja100716x
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发表时间：
2010-04
影响因子：
15
通讯作者：
Mingxiang Zhu;Junfeng Zhao;T. Loh
中科院分区：
文献类型：
--
作者：
Mingxiang Zhu;Junfeng Zhao;T. Loh
本文介绍了在极温和条件下，以1atm空气为唯一氧化剂，钯催化肟辅助烯烃分子内双氧反应，证明了在室温下1atm空气条件下，将大气氧加入合成有用产物的可行性。
This paper describes a palladium-catalyzed oxime assisted intramolecular dioxygenation of alkenes by using 1 atm of air as the sole oxidant under extremely mild conditions, which demonstrated the feasibility of incorporating atmospheric oxygen into synthetically useful products under 1 atm of air at room temperature.