Metal-Free [3+2] Oxidative Coupling of Phenols with Alkenes: Synthesis of Dihydrobenzofurans

Metal-Free [3+2] Oxidative Coupling of Phenols with Alkenes: Synthesis of Dihydrobenzofurans
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无金属 [3 2] 酚与烯烃的氧化偶联:二氢苯并呋喃的合成

DOI:
10.1055/s-0034-1380419
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发表时间:
2015
影响因子:
2.6
通讯作者:
Xia Wujiong
Xia Wujiong
中科院分区:
化学4区
文献类型:
--
作者:
Zhao Yating;Huang Binbin;Yang Chao;Li Bing;Xia Wujiong

文献摘要

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Abstract Herein, we demonstrated a benign and metal-free [3+2]-cycloaddition reaction using simple and readily available phenols and styrenes as substrates and sodium persulfate as an inexpensive and environmentally friendly oxidant for the direct synthesis of dihydrobenzofurans. This methodology was applied to the synthesis of corsifuran A in a single step.