Collisional activation mass spectra of ions containing polyisotopic elements

Collisional activation mass spectra of ions containing polyisotopic elements
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含有多同位素元素的离子的碰撞激活质谱

DOI:
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发表时间:
1982
期刊:
影响因子:
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通讯作者:
F. McLafferty
F. McLafferty
中科院分区:
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文献类型:
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作者:
P. Todd;M. Barbalas;F. McLafferty

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如果含有元素的多个同位素的质量选择离子由于失去含有该元素的中性而碎裂,则产物离子将被观察为多个峰。这种峰的“同位素簇”,虽然与正常质谱中发现的峰的外观不同,但也表明了前体离子的同位素组成。
If a mass selected ion containing multiple isotopes of an element fragments by loss of a neutral containing the element, the product ions will be observed as multiple peaks. This ‘isotopic cluster’ of peaks, although of a different appearance than those found in normal mass spectra, also indicates the isotopic composition of the precursor ion.