Reaction pathway studies of C6 hydrocarbons on palladium model catalysts: effects of hydrogen/hydrocarbon ratio, molecular structure, surface structure and temperature

Reaction pathway studies of C6 hydrocarbons on palladium model catalysts: effects of hydrogen/hydrocarbon ratio, molecular structure, surface structure and temperature
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C6烃在钯模型催化剂上的反应路径研究:氢/烃比、分子结构、表面结构和温度的影响

DOI:
10.1023/a:1019091305212
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发表时间:
2000
期刊:
影响因子:
--
通讯作者:
G. Somorjai
G. Somorjai
中科院分区:
--
文献类型:
--
作者:
A. Ramos;S. Kim;Pei;Jae Hee Song;G. Somorjai

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在小比表面积Pd(111)单晶和多晶Pd箔模型催化剂上研究了C6烃的氢解、脱氢、芳构化和脱氢环化等反应途径。这些反应在间歇式反应器中,在大气压和两个不同的温度(573和673 K)下进行。
Reaction pathways of C6hydrocarbons, such as hydrogenolysis, dehydrogenation, aromatization and dehydrocyclization, have been studied on small surface area palladium model catalysts, including Pd(111) single crystal and polycrystalline palladium foil. These reactions were performed in a batch reactor, at atmospheric pressure and at two different temperatures (573 and 673 K).