Consequences of Partial Flexibility in 1,3-Benzenedicarboxylate Linkers: Kagomé Lattice and NbO Supramolecular Isomers from Complexation of a Bulky 1,3-Benzenedicarboxylate to Cu(II) Paddlewheel Moieties
Consequences of Partial Flexibility in 1,3-Benzenedicarboxylate Linkers: Kagomé Lattice and NbO Supramolecular Isomers from Complexation of a Bulky 1,3-Benzenedicarboxylate to Cu(II) Paddlewheel Moieties
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DOI：
10.1021/cg200183x
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发表时间：
2011-03
影响因子：
3.8
通讯作者：
Zhenjie Zhang;L. Wojtas;M. Zaworotko
中科院分区：
文献类型：
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作者：
Zhenjie Zhang;L. Wojtas;M. Zaworotko
5-取代苯-1，3-二羧酸(1，3-BDC)，5-(N-邻苯二甲酰亚胺)间苯二甲酸(5-NPIA)与CuCl2反应生成Kagome晶格或NBO网络，这取决于反应所用的溶剂。
A 5-substituted benzene-1,3-dicarboxylic acid (1,3-BDC), 5-(N-phthalimide)isophthalic acid (5-NPIA), reacts with CuCl2 to afford either a Kagome lattice or NbO nets, depending upon which solvent is used for the reaction.