EXPERIMENTAL-STUDY AND KINETIC MODELING OF PROPENE OXIDATION IN A JET STIRRED FLOW REACTOR
EXPERIMENTAL-STUDY AND KINETIC MODELING OF PROPENE OXIDATION IN A JET STIRRED FLOW REACTOR
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DOI：
10.1021/j100314a019
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发表时间：
1988-02-11
影响因子：
--
通讯作者：
BOETTNER, JC
中科院分区：
文献类型：
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作者：
DAGAUT, P;CATHONNET, M;BOETTNER, JC
The oxidation of propene was studied in a jet stirred flow reactor in the temperature range 900-1200 K at pressures extending from 1 to 8 atm for a wide range of fuel-oxygen equivalence ratios (0.15-4.0). A computer program has been developed to model the experimental data by using a chemical kinetic reaction mechanism. A direct method to determine the first-order sensitivities of the mole fraction of eachspecies with respect to the rate constants was used to develop the kinetic scheme. The present chemical kinetic reaction mechanism is able to reproduce the experimental results, although some discrepancies are observed for the minor products.
