Hydrothermal synthesis and crystal structure of a new two-dimensional zinc citrate complex
Hydrothermal synthesis and crystal structure of a new two-dimensional zinc citrate complex
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DOI：
10.1080/00958970500244112
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发表时间：
2005-11-01
影响因子：
1.9
通讯作者：
Meng, J
中科院分区：
文献类型：
--
作者：
Che, P;Fang, DQ;Meng, J
采用水热法合成了一种新的含七配位锌原子的二维化合物C_（12）H_（14）O_（16）Zn_3（1）。用TG-DTA、X射线单晶衍射、元素分析和FT-IR对产物进行了表征。单晶X射线衍射分析表明，化合物1为单斜晶系，空间群为P2（1）/c，a = 6.1552（13）埃，B = 14.546（3）埃，c = 9.581埃，β = 102.66（2）度，V = 836.9（4）埃（3），Z = 2，R1 = 0.0311，wR2 = 0.0830。
new two-dimensional compound C12H14O16Zn3 ( 1), containing seven-coordinate zinc atoms was prepared by the hydrothermal technique. The compound obtained was characterized by TG-DTA, single crystal X-ray diffraction, elemental analysis and FT-IR analysis. Single-crystal X-ray diffraction analysis shows that compound 1 crystallizes with monoclinic symmetry in the space group P2(1)/c, a = 6.1552(13) angstrom, b = 14.546(3) angstrom, c = 9.581 angstrom, beta = 102.66(2)degrees, V = 836.9(4) angstrom(3), Z = 2, R1 = 0.0311, wR2 = 0.0830.