Metallasupramolecular architectures, an overview of functional properties and applications

Metallasupramolecular architectures, an overview of functional properties and applications
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DOI:
10.1039/b505354d
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发表时间:
2006-01-01
影响因子:
4
通讯作者:
van Koten, G
van Koten, G
中科院分区:
化学2区
文献类型:
--
作者:
Amijs, CHM;van Klink, GPM;van Koten, G

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在过去的十年里,金属超分子结构的合成,如二维正方形、三角形和多边形,以及三维笼形和多面体,引起了人们极大的兴趣。这些结构被设计成具有新颖的特定形状和尺寸,具有有趣的功能特性。在这篇综述中,突出了metallasupramolecular架构的功能特性,重点是潜在的应用,如催化,腔定向合成和传感,可以与这些材料进行。
The synthesis of metallasupramolecular architectures, such as two-dimensional squares, triangles and polygons, and three-dimensional cages and polyhedra, has attracted much interest in the past decade. These structures are designed to have novel specific shapes and dimensions with interesting functional properties. In this overview the functional properties of metallasupramolecular architectures are highlighted with emphasis on potential applications such as catalysis, cavity-directed synthesis and sensing, that can be performed with these materials.