SYNTHESES AND CHARACTERIZATION OF AMMONIUM AND TETRAALKYLAMMONIUM THIOMOLYBDATES AND THIOTUNGSTATES
SYNTHESES AND CHARACTERIZATION OF AMMONIUM AND TETRAALKYLAMMONIUM THIOMOLYBDATES AND THIOTUNGSTATES
复制标题
DOI：
10.1016/s0020-1693(00)81720-x
复制
发表时间：
1983-01-01
期刊：
影响因子：
--
通讯作者：
NEWTON, WE
中科院分区：
文献类型：
--
作者：
MCDONALD, JW;FRIESEN, GD;NEWTON, WE
综述了[NH_4]_2[MO_2S_2]和[NH_4]_2[MS_4]的合成方法，并报道了[NH_4]_2[MOS_3]（M = Mo，W）的新合成方法。[NH_4]~+盐通过与[Et_4N]OH水溶液的反应容易地转化为[Et_4N]~+盐。红外光谱和电子光谱数据的thiridylates总结作为一种援助，以未来的表征。
Improved methods for the preparation of [NH4]2[MO2S2] and [NH4]2[MS4] are summarized and new syntheses of [NH4]2[MOS3] are reported (M = Mo, W). The facile conversion of the [NH4]+salts to [Et4N]+saltsviareaction with aqueous [Et4N]OH is also described. Infrared and electronic spectral data for the thiometallates are summarized as an aid to future characterization.