Valence tautomeric transitions with thermal hysteresis around room temperature and photoinduced effects observed in a cobalt-tetraoxolene complex
Valence tautomeric transitions with thermal hysteresis around room temperature and photoinduced effects observed in a cobalt-tetraoxolene complex
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DOI：
10.1021/ja057488u
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发表时间：
2006-02-15
影响因子：
15
通讯作者：
Sato, O
中科院分区：
文献类型：
--
作者：
Tao, J;Maruyama, H;Sato, O
成功合成了一种双核配合物[(CoTPA)2(DHBQ)](PF6)3，该配合物在室温下表现出明显的价互变效应（13 K），在低温下表现出光诱导价互变效应。
A dinuclear complex, [(CoTPA)2(DHBQ)](PF6)3, has been successfully synthesized that exhibits a valence tautomeric transition with a distinct hysteresis effect (13 K) around room temperature and photoinduced valence tautomerism under low temperature.