A free-radical-promoted stereospecific denitro silylation of beta-nitroalkenes with silanes
A free-radical-promoted stereospecific denitro silylation of beta-nitroalkenes with silanes
复制标题
自由基促进的β-硝基烯烃与硅烷的立体定向脱硝基硅烷化反应
DOI：
10.1039/c9qo00819e
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发表时间：
2019
影响因子：
5.4
通讯作者：
Quan Zheng Jun
中科院分区：
文献类型：
--
作者：
Zhang Xi;Liu Ming Xia;Wang Tong Lin;Wang Yong Qing;Wang Xi Cun;Quan Zheng Jun
以DTBP为氧化剂，Cu催化β-硝基烯烃与硅烷的立体定向双硅烷基化反应合成了乙烯基硅烷。该方法提供了一种廉价、无毒的催化体系，具有合适的底物范围。这种方法是（E）-特异性的，并且以良好的产率生产了一类重要的乙烯基硅烷。
A Cu-catalyzed stereospecific denitro silylation of β-nitroalkenes with silanes for the synthesis of vinylsilanes using DTBP as the oxidant was developed. This method presented an inexpensive and non-toxic catalytic system with an appropriate substrate scope. This approach is (E)-specific and produced an important class of vinylsilanes in good yields.