[BEDT-TTF][Fe(C2O4)Cl2]: An Organic-Inorganic Hybrid Semiconductive Antiferromagnet
[BEDT-TTF][Fe(C2O4)Cl2]: An Organic-Inorganic Hybrid Semiconductive Antiferromagnet
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[BEDT-TTF][Fe(C2O4)Cl2]：有机-无机混合半导体反铁磁体
DOI：
10.1039/c6dt01845a
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发表时间：
2016
影响因子：
4
通讯作者：
T. Mori
中科院分区：
文献类型：
--
作者：
B. Zhang;Y. Zhang;Z. Wang;D. Yang;Z. Gao;D. Wang;Y. Guo;D. Zhu;T. Mori
采用电结晶法得到了有机给体BEDT-TTF1.0+和一维无机阴离子[Fe(C2O4)Cl2−]n组成的阳离子盐，其值为σ300K = 3.0 × 10−5 S cm−1。ZFCM/FCM/RM测量在5.5 K下观察到自旋倾斜的反铁磁远程有序，并通过交流测量证实。
A radical cation salt composed of an organic donor, BEDT-TTF1.0+, and a one-dimensional inorganic anion, [Fe(C2O4)Cl2−]n, was obtained by electrocrystallization, and was identified as a semiconductor with values of σ300K = 3.0 × 10−5 S cm−1. Spin-canted antiferromagnetic long-range ordering was observed at 5.5 K from ZFCM/FCM/RM measurement and confirmed using AC measurement.