Multicomponent Assembly of Heterometallic Isosceles Triangles
Multicomponent Assembly of Heterometallic Isosceles Triangles
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DOI：
10.1021/ic8021084
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发表时间：
2009-02-02
影响因子：
4.6
通讯作者：
Mahata, Kingsuk
中科院分区：
文献类型：
--
作者：
Schmittel, Michael;Mahata, Kingsuk
阐述了三种等腰三角形双杂金属超分子化合物的多组分合成和溶液态表征。三角形组件是等腰几何和化学;它们包括多个配体，金属，和结合图案。通过改变苯基间隔物的数量n = 0、1和2来改变三角形的一侧的长度，影响相对的铜（I）中心的氧化还原电位，允许将纳米机械变化转化为电子可读值。
The multicomponent synthesis and solution-state characterization of three supramolecular bis-heterometallic isosceles triangles are elaborated. The triangular assemblies are isosceles both geometrically and chemically; they comprise multiple ligands, metals, and binding motifs. Variation of the length of one side of the triangle by changing the number of phenyl spacers n = 0, 1, and 2 influences the redox potential of the opposing copper(I) center, allowing translation of the nanomechanical changes into electronically readable values.