Fixation of atmospheric carbon dioxide by ruthenium complexes bearing an NHC-based pincer ligand: formation of a methylcarbonato complex and its methylation
Fixation of atmospheric carbon dioxide by ruthenium complexes bearing an NHC-based pincer ligand: formation of a methylcarbonato complex and its methylation
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DOI：
10.1039/c5dt00476d
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发表时间：
2015-01-01
影响因子：
4
通讯作者：
Umakoshi, Keisuke
中科院分区：
文献类型：
--
作者：
Arikawa, Yasuhiro;Nakamura, Takuo;Umakoshi, Keisuke
通过使用（CNC）（bpy）Ru支架从空气中捕获CO2来制备碳酸甲酯钌络合物。碳酸甲酯络合物对脱羧反应相对惰性。用甲基化试剂处理释放碳酸二甲酯。
A methylcarbonato ruthenium complex was prepared by capture of CO2 from air using the (CNC)(bpy)Ru scaffold. The methylcarbonato complex was relatively inert to decarboxylation. Treatments with methylating reagents released dimethylcarbonate.