CO2 selectivity of a 1D microporous adenine-based metal-organic framework synthesised in water

CO2 selectivity of a 1D microporous adenine-based metal-organic framework synthesised in water
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DOI:
10.1039/c0cc05559j
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发表时间:
2011-01-01
影响因子:
4.9
通讯作者:
Rosseinsky, Matthew J.
Rosseinsky, Matthew J.
中科院分区:
化学2区
文献类型:
--
作者:
Stylianou, Kyriakos C.;Warren, John E.;Rosseinsky, Matthew J.

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The coordination of adenine to Ni2+ forms a dimer unit which can be linked by 3,5-pyrazoledicarboxylic acid into chains which assemble under hydrothermal conditions via hydrogen bonding into a robust porous network. The material displays selectivity for CO2 over CH4 and an isosteric heat which increases with guest loading.