An interlaboratory study evaluating the interpretation of forensic glass evidence using refractive index measurements and elemental composition.

An interlaboratory study evaluating the interpretation of forensic glass evidence using refractive index measurements and elemental composition.
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DOI:
10.1016/j.forc.2021.100307
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发表时间:
2021-03
期刊:
Forensic chemistry (Amsterdam, Netherlands)
影响因子:
--
通讯作者:
Almirall J
Almirall J
中科院分区:
其他
文献类型:
--
作者:
Corzo R;Hoffman T;Ernst T;Trejos T;Berman T;Coulson S;Weis P;Stryjnik A;Dorn H;Pollock EC;Workman MS;Jones P;Nytes B;Scholz T;Xie H;Igowsky K;Nelson R;Gates K;Gonzalez J;Voss LM;Almirall J

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十七个实验室参加了三个实验室间的演习,以评估折射率,微X射线荧光光谱(μXRF)和激光诱导击穿光谱(LIBS)数据的性能,用于玻璃样品的法医比较。来自汽车挡风玻璃的玻璃碎片作为盲样分发给参与实验室,参与者被要求比较玻璃样品(已知与质疑),并报告他们的调查结果,就像他们在个案工作中一样。对于来自同一来源的样品,三种技术(折射率、μXRF和LIBS)的总体正确关联率均大于92%。对于来自不同车辆的样品,观察到折射率、μXRF和LIBS的总体正确排除率分别为82%、96%和87%。特别注意从业人员使用的报告语言以及使用口头量表和/或数据库来确定证据的重要性。不同实验室之间报告的结论存在很大差异,这表明从业人员使用的报告语言需要标准化。此外,很少有实验室使用口头量表和/或数据库来为证据提供权重。建议法医从业人员努力使用口头量表和/或背景数据库(如果有的话),以提供对玻璃法医证据的重要性的衡量标准(即,关联或排斥的强度)。
Seventeen laboratories participated in three interlaboratory exercises to assess the performance of refractive index, micro X-ray Fluorescence Spectroscopy (μXRF), and Laser Induced Breakdown Spectroscopy (LIBS) data for the forensic comparison of glass samples. Glass fragments from automotive windshields were distributed to the participating labs as blind samples and participants were asked to compare the glass samples (known vs. questioned) and report their findings as they would in casework. For samples that originated from the same source, the overall correct association rate was greater than 92% for each of the three techniques (refractive index, μXRF, and LIBS). For samples that originated from different vehicles, an overall correct exclusion rate of 82%, 96%, and 87% was observed for refractive index, μXRF, and LIBS, respectively. Special attention was given to the reporting language used by practitioners as well as the use of verbal scales and/or databases to assign a significance to the evidence. Wide variations in the reported conclusions exist between different laboratories, demonstrating a need for the standardization of the reporting language used by practitioners. Moreover, few labs used a verbal scale and/or a database to provide a weight to the evidence. It is recommended that forensic practitioners strive to incorporate the use of a verbal scale and/or a background database, if available, to provide a measure of significance to glass forensic evidence (i.e., the strength of an association or exclusion).
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