Anion carrier mediated membrane transport of phosphate: selectivity of H2PO4- over Cl-
Anion carrier mediated membrane transport of phosphate: selectivity of H2PO4- over Cl-
复制标题
DOI：
10.1021/ja00104a040
复制
发表时间：
1994-12
影响因子：
15
通讯作者：
H. Visser;D. Rudkevich;W. Verboom;F. D. Jong;D. Reinhoudt
中科院分区：
文献类型：
--
作者：
H. Visser;D. Rudkevich;W. Verboom;F. D. Jong;D. Reinhoudt
出现了许多关于通过中性阳离子载体介导的支撑液膜（SLM）选择性传输盐的论文。在由中性阳离子载体如简单冠醚、杯芳烃或天然离子载体如缬氨霉素辅助的转运中，由于不同的脱水能，阴离子影响转运速率。因此，亲脂性阴离子如ClO 4-、NO3-或SCN-通常用作抗衡离子。亲脂性差得多的阴离子如Cl-或H2 PO 4-仅通过离子交换机制被带电阴离子载体（AC）转运，2-4并且转运选择性遵循Hofmeister系列：5优选（H2 PO 4-）阴离子有机溶剂，刘易斯布朗斯台德酸性和H2 PO 4-的组合作用。
numerous papers appeared on the selective transport of salts through supported liquid membranes (SLMs) mediated by neutral cation carriers. In transport assisted by neutral cation carriers such as simple crown ethers, calixarenes, or natural ionophores like valinomycin, anions affect the transport rates because of the different dehydration energies. Therefore, lipophilic anions like CIO4-, NO3-, or SCN- are often used as the counterion. Much less lipophilic anions like Cl- or H2PO4-have only been transported by charged anion carriers (ACs) via an ion-exchange mechanism,2-4 and the transport selectivity follows the Hofmeister series:5 prefer-entially (H2PO4-) anions organic solvents the combined action of Lewis Br0nsted acidic the