Parametric study for saline water electrolysis: Part II—Chlorine evolution, selectivity and determination
Parametric study for saline water electrolysis: Part II—Chlorine evolution, selectivity and determination
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DOI：
10.1016/0360-3199(93)90172-7
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发表时间：
1993-07
影响因子：
7.2
通讯作者：
H. Abdel-aal;S. M. Sultan;I. Hussein
中科院分区：
文献类型：
--
作者：
H. Abdel-aal;S. M. Sultan;I. Hussein
电解浓氯溶液对氯析出的影响是本文的主要主题。用碘量法和抗坏血酸滴定实验测定了气相中析出的氯量和溶解在溶液中的氯量。建立了含氯量与盐水含氯量之间的关系式。氢氯比被确定为电池性能的标准。
The effect of electrolyzing concentrated chloride solutions as far as the evolution of chlorine is the main theme of this paper. Experimental determination of the amount of chlorine evolved in the gas phase and chlorine dissolved in solution is achieved using the iodometry and ascorbinometric titrations. Correlations are developed for the chlorine content as a function of the chloride concentration of the saline water. The hydrogen to chlorine ratio is determined as a criteria for the cell performance.