Optically Active Organometallic Compounds of Transition Elements with Chiral Metal Atoms.
Optically Active Organometallic Compounds of Transition Elements with Chiral Metal Atoms.
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DOI：
10.1002/(sici)1521-3773(19990503)38:9
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发表时间：
1999-05
影响因子：
--
通讯作者：
H. Brunner
中科院分区：
文献类型：
--
作者：
H. Brunner
手性过渡金属原子不仅存在于Alfred Werner已经拆分成对映体的三配位配合物[M(LL)3]n+中，而且还存在于具有三条或四条腿钢琴凳结构的有机金属半夹心配合物中。这些络合物已经成为解释反应空间过程和有机合成的工具。在对映体选择性催化中的应用开始显现。
Chiral transition metal atoms are not only present in tris-chelate complexes [M(LL)3 ]n+ , which were already resolved into the enantiomers by Alfred Werner, but also in organometallic half-sandwich complexes such as 1 with three- or four-legged piano-stool structure. These complexes have been tools in the elucidation of the spatial course of reactions and in organic syntheses. Applications in enantioselective catalysis are beginning to show up.