Alkali-Metal Mediation: Diversity of Applications in Main-Group Organometallic Chemistry.
Alkali-Metal Mediation: Diversity of Applications in Main-Group Organometallic Chemistry.
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DOI：
10.1002/anie.202010963
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发表时间：
2021-04-19
期刊：
影响因子：
--
通讯作者：
Mulvey RE
中科院分区：
文献类型：
--
作者：
Gentner TX;Mulvey RE
一个多世纪以来，有机锂化合物一直处于合成化学的前沿，因为它们介导了全世界学术和工业环境中使用的无数化合物的合成。因此，锂一直是有机金属化学中最重要的碱金属。如今，这种重要性正受到钠和钾的严重挑战，因为一般有机反应的碱金属介导已经开始向几个新的方向分支。本综述展示了最近的例子，涵盖主族均相催化、化学计量有机合成、低价主族金属化学、聚合和绿色化学。由于碱金属化合物通常不是这些应用的最终产品，因此它们的作用很少受到重视。因此，撰写这篇评论是为了提醒社会注意这种日益兴起的“碱金属调解”统一现象。在调节反应方面，碱金属名列前茅。有机锂化合物长期以来一直是它们的领军者，但现在有机钠和有机钾化合物也正在寻找它们的形式。这篇综述强调了他们在均相催化、有机合成、低价铝化学、聚合和绿色化学方面的胜利。
Organolithium compounds have been at the forefront of synthetic chemistry for over a century, as they mediate the synthesis of myriads of compounds that are utilised worldwide in academic and industrial settings. For that reason, lithium has always been the most important alkali metal in organometallic chemistry. Today, that importance is being seriously challenged by sodium and potassium, as the alkali‐metal mediation of organic reactions in general has started branching off in several new directions. Recent examples covering main‐group homogeneous catalysis, stoichiometric organic synthesis, low‐valent main‐group metal chemistry, polymerization, and green chemistry are showcased in this Review. Since alkali‐metal compounds are often not the end products of these applications, their roles are rarely given top billing. Thus, this Review has been written to alert the community to this rising unifying phenomenon of “alkali‐metal mediation”. Alkali metals top the league when it comes to mediating reactions. Organolithium compounds have long been their captain, but now organosodium and organopotassium compounds are finding their form too. This Review highlights their victories in homogeneous catalysis, organic synthesis, low‐valent aluminium chemistry, polymerization, and green chemistry.
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影响因子：
4.5
作者：
Anga, Srinivas;Sarazin, Yann;Panda, Tarun K.
通讯作者：
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影响因子：
4.9
作者：
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通讯作者：
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DOI：
10.1039/c39920000204
发表时间：
1992-01-15
影响因子：
--
作者：
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通讯作者：
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影响因子：
2.3
作者：
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通讯作者：
Wakefield, BJ
影响因子：
37.8
作者：
Asako, Sobi;Nakajima, Hirotaka;Takai, Kazuhiko
通讯作者：
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