ANALYSIS OF ALIPHATIC PER ACIDS

ANALYSIS OF ALIPHATIC PER ACIDS
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DOI:
10.1021/ac60023a020
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发表时间:
1948-01-01
影响因子:
7.4
通讯作者:
MACKELLAR, DG
MACKELLAR, DG
中科院分区:
化学1区
文献类型:
--
作者:
GREENSPAN, FP;MACKELLAR, DG

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过酸溶液分析的新方法是基于使用硫酸高铈作为过氧化氢存在的滴定剂,然后通过碘量法测定过酸存在。数据显示的分析结果,样品每酸的建议方法相比,高锰酸钾-硫代硫酸盐法的D 'Ans和弗雷。新方法给出了更高、更可靠的值。
A new method for the analysis of per acid solutions is based upon the use of ceric sulfate as a titrant for the hydrogen peroxide present, followed by an iodometric determination of the per acid present. Data are presented showing the results of analyses of sample per acids by the proposed method compared to the potassium permanganate-thiosulfate method of D’Ans and Frey. The new method gives higher, more reliable values.