Complexation of stable carbenes with alkali metals

Complexation of stable carbenes with alkali metals
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DOI:
10.1039/a808951e
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发表时间:
1999-02-07
影响因子:
4.9
通讯作者:
Quayle, MJ
Quayle, MJ
中科院分区:
化学2区
文献类型:
--
作者:
Alder, RW;Blake, ME;Quayle, MJ

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稳定的二氨基烃类,包括咪唑-2-吡啶类,可与锂、钠和钾络合;报道了1,3-二异丙基-3,4,5,6-四氢嘧啶-2-基二烯- 1与KN(SiMe3)(2)配合物的晶体结构。
Stable diaminocarbenes, including imidazol-2-ylidenes, undergo complexation with lithium, sodium and potassium species; the crystal structure of a complex of 1,3-diisopropyl-3,4,5,6-tetrahydropyrimid-2-ylidene 1 with KN(SiMe3)(2) is reported.