1H and 13C chemical shifts of some bicyclo[4.3.0]- and bicyclo[6.3.0]-γ-lactones and α-carbomethoxy-γ-lactones

1H and 13C chemical shifts of some bicyclo[4.3.0]- and bicyclo[6.3.0]-γ-lactones and α-carbomethoxy-γ-lactones
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DOI:
10.1002/(sici)1097-458x(199806)36:6
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发表时间:
1998-06-01
影响因子:
2
通讯作者:
Faure, R
Faure, R
中科院分区:
化学3区
文献类型:
--
作者:
Lamarque, L;Campredon, M;Faure, R

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结合同核(GS-COSY)、H-1检测的异核单键(GS-HMQC)和长程(GS-HMBC)相关实验,对十个双环[4.3.0]-和[6.3.0]-双环-伽马-内酯和α-甲氧基-伽马-内酯的H-1和C-13核磁共振波谱进行了完全和明确的归属。(C)1998年John Wiley&Sons,Ltd.
The H-1 and C-13 NMR resonances of ten bicyclo[4.3.0]- and bicyclo[6.3.0]-gamma-lactones and alpha-carbomethoxy-gamma-lactones were completely and unambiguously assigned by a combination of homonuclear (gs-COSY), H-1-detected heteronuclear one-bond (gs-HMQC) and long-range (gs-HMBC) gradient-selected correlation experiments. (C) 1998 John Wiley & Sons, Ltd.