Epoxide intermediates in microsomal oxidation of olefins to glycols.
Epoxide intermediates in microsomal oxidation of olefins to glycols.
复制标题
烯烃微粒体氧化成二醇的环氧化物中间体。
DOI：
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发表时间：
1970
影响因子：
3.5
通讯作者：
E. Ortiz
中科院分区：
文献类型：
--
作者：
K. Leibman;E. Ortiz
The oxidation in rabbit liver microsomes of styrene, cyclohexene and indene to epoxides has been demonstrated by gas chromatography, by thin-layer chromatography of the epoxide picrate derivatives and by accumulation of radioactivity in a styrene oxide pool from labeled styrene. Hydration of these epoxides to glycols had previously been demonstrated; in the cases of the cycloalkenes, the glycol products were the same isomers as those formed by overall oxidation of the alkenes. Epoxides are therefore intermediates in the oxidation of these alkenes to glycols in liver microsomes.
