cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe III and Pd II coordination clusters.
cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe III and Pd II coordination clusters.
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DOI：
10.1039/b815200d
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发表时间：
2009-02
影响因子：
4
通讯作者：
Graham N. Newton;Geoffrey J T Cooper;Dominik Schuch;Takuya Shiga;S. Khanra;D. Long;H. Oshio;L. Cronin
中科院分区：
文献类型：
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作者：
Graham N. Newton;Geoffrey J T Cooper;Dominik Schuch;Takuya Shiga;S. Khanra;D. Long;H. Oshio;L. Cronin
使用高度支化的十五齿螯合配体 cis,cis-1,3,5-环己烷三胺-N,N,N',N',N'',N''-六乙酸 (H(6)hact) 合成了十二核 Fe(III) 配合物，该配合物由通过单个羟基桥耦合的两个 {Fe(6)} 单元和笼状 Pd(II) 三聚体组成。
A dodecanuclear Fe(III) complex, consisting of two {Fe(6)} units coupled across a single hydroxy-bridge and a cage-like Pd(II) trimer were synthesised using the highly branched, pentadecadentate chelating ligand cis,cis-1,3,5-cyclohexanetriamine-N,N,N',N',N'',N''-hexaacetic acid (H(6)hact).