Solubilization of elemental sulfur by surfactants promotes reduction to H 2 S by thiols
Solubilization of elemental sulfur by surfactants promotes reduction to H 2 S by thiols
复制标题
表面活性剂对元素硫的溶解促进硫醇还原成H 2 S
DOI：
10.1039/d3cc01914d
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发表时间：
2023
影响因子：
4.9
通讯作者：
Pluth, Michael D.
中科院分区：
文献类型：
--
作者：
Garcia, Arman C.;Pluth, Michael D.
元素硫(S8)可能对生物体系中硫烷硫(S0)的储存有贡献。我们证明了表面活性剂能使S8在水中增溶，并促进S8被硫醇还原为H_2S。此外，阴离子和阳离子表面活性剂与中间S0载体的相互作用不同，突出了特定的疏水微环境如何影响活性硫物种。
Elemental sulfur (S8) may contribute to sulfane sulfur (S0) storage in biological systems. We demonstrate that surfactants can solubilize S8 in water and promote S8 reduction to H2S by thiols. Moreover, anionic and cationic surfactants interact differently with intermediate S0 carriers, highlighting how specific hydrophobic microenvironments impact reactive sulfur species.