Self-assembly of tripyrazolate-linked macrotricyclic M(12)L(4) cages with dimetallic clips.
Self-assembly of tripyrazolate-linked macrotricyclic M(12)L(4) cages with dimetallic clips.
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DOI：
10.1021/ol070286d
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发表时间：
2007-02
期刊：
影响因子：
5.2
通讯作者：
Shu‐Yan Yu;Qing Jiao;Sheng-Hui Li;Hai-Ping Huang;Yi-zhi Li;Yuan-jiang Pan;Y. Sei;K. Yamaguchi
中科院分区：
文献类型：
--
作者：
Shu‐Yan Yu;Qing Jiao;Sheng-Hui Li;Hai-Ping Huang;Yi-zhi Li;Yuan-jiang Pan;Y. Sei;K. Yamaguchi
[结构：见正文]。通过1H NMR、13 C NMR、冷喷雾电离质谱（CSI-MS）和单晶X-射线分析证实了三吡唑三阴离子连接体（H3 L = 1和2）与配位双金属夹在水溶液中的自组装导致形成具有1800埃3和1500埃3的内腔的Pd 12 L4笼。
[structure: see text]. The self-assembly in aqueous solution of tripyrazolate trianion linkers (H3L = 1 and 2) with coordinated dimetallic clips leads to the formation of Pd12L4 cages with interior cavities of 1800 Angstroms3 and 1500 Angstroms3, respectively, confirmed by 1H NMR, 13C NMR, cold spray ionization mass spectrometry (CSI-MS), and single-crystal X-ray analysis.