Comparison of 2-Arylnaphtho[2,3-b]phospholes and 2-Arylbenzo[b]phospholes: Effects of 2-Aryl Groups and Fused Arene Moieties on Their Optical and Photophysical Properties
Comparison of 2-Arylnaphtho[2,3-b]phospholes and 2-Arylbenzo[b]phospholes: Effects of 2-Aryl Groups and Fused Arene Moieties on Their Optical and Photophysical Properties
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DOI：
10.1021/acs.joc.5b00541
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发表时间：
2015-06-05
影响因子：
3.6
通讯作者：
Kimura, Yoshifumi
中科院分区：
文献类型：
--
作者：
Matano, Yoshihiro;Motegi, Yuta;Kimura, Yoshifumi
利用Suzuki-Miyaura交叉偶联反应合成了一系列2-芳基萘并[2，3-B]磷杂环戊烯P-氧化物及其苯并[B]磷杂环戊烯衍生物。我们阐明了2-芳基基团和稠合芳烃基团对这两种类型的基于磷脂的π-体系的光学和物理性质的电子和空间效应。
Suzuki-Miyaura cross-coupling reactions were used in the divergent synthesis of a series of 2-arylnaphtho[2,3-b]phosphole P-oxides and their benzo[b]phosphole counterparts. We elucidated the electronic and steric effects of the 2-aryl groups and fused arene moieties on the optical and photophysical properties of these two types of phosphole-based pi-systems.