Effect of pressure on the proton-proton vicinal coupling constants in 1,1,2-trichloroethane and 1,1,2,2-tetrachloroethane-1-13C. A new approach to high-pressure study of molecular conformations
Effect of pressure on the proton-proton vicinal coupling constants in 1,1,2-trichloroethane and 1,1,2,2-tetrachloroethane-1-13C. A new approach to high-pressure study of molecular conformations
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压力对 1,1,2-三氯乙烷和 1,1,2,2-四氯乙烷-1-13C 中质子-质子邻位耦合常数的影响。
DOI：
10.1021/ja00230a054
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发表时间：
1988
影响因子：
15
通讯作者：
A. Sera
中科院分区：
文献类型：
--
作者：
H. Yamada;T. Kazuoka;A. Sera
图 2. 45 C 时压力对 1, 1, 2-三氯乙烷 In K 的影响。空心圆圈指未校正的数据。十字是指经过“失真”校正的数据，使用 K=(J¡+(1.5 X 10'3)/>-7vic)/(yvic-J¡ i) 计算。虚线描绘了 45 C 下高压红外实验的结果。 12
Figure 2. Pressure effect on In K for 1, 1, 2-trichloroethane at 45 C. Open circles refer to uncorrected data. Crosses refer to “distortion”-corrected data, calculated by using K=(J¡+(1.5 X 10'3)/>-7vic)/(yvic-J¡ i). The dotted line depicts the result of a high-pressure IR experiment at 45 C. 12