"Cation pool" method based on C-C bond dissociation. Effective generation of monocations and dications
"Cation pool" method based on C-C bond dissociation. Effective generation of monocations and dications
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DOI：
10.1021/ja050414y
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发表时间：
2005-05-18
影响因子：
15
通讯作者：
Yoshida, J
中科院分区：
文献类型：
--
作者：
Okajima, M;Suga, S;Yoshida, J
烷氧基芳基碳正离子的“阳离子池”是通过使用低温电解的氧化性C-C键解离有效地产生的。本方法对于与碳亲核试剂反应的双阳离子的产生和积累特别有效。
The “cation pools” of alkoxyarylcarbenium ions were effectively generated by the oxidative C−C bond dissociation using low temperature electrolysis. The present method is especially effective for the generation and accumulation of dications, which react with carbon nucleophiles.