The electrical properties of some cordierite glass ceramics in the system MgO-Al2O3-SiO2-TiO2

The electrical properties of some cordierite glass ceramics in the system MgO-Al2O3-SiO2-TiO2
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MgO-Al2O3-SiO2-TiO2体系中部分堇青石微晶玻璃的电性能

DOI:
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发表时间:
1990
期刊:
影响因子:
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通讯作者:
R. Freer
R. Freer
中科院分区:
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文献类型:
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作者:
I. O. Owate;R. Freer

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的交流用三组不同结晶度的样品研究了MgO-Al_2 O_3-SiO_2-TiO_2系统微晶玻璃的介电击穿和电阻率。标准交流(50 Hz)击穿测试在室温(18 °C)下使用平面圆盘试样和半球形端部黄铜接触电极进行。击穿过程导致形成的击穿通道终止于试样表面的弹坑。击穿强度与电压上升速率无关,但随着试样厚度的增加呈指数下降(60至10 kV mm−1)。高的结晶度含量,良好的表面光洁度和均匀的微观结构产生高的击穿强度,而不良的微观结构的发展造成的击穿强度降低。击穿机制被认为是电子、热和机电过程的组合。
The a.c. dielectric breakdown and electrical resistivity of glass ceramics in the system MgO-Al2O3-SiO2-TiO2 have been studied using three sets of samples having different crystallinity contents. Standard a.c. (50 Hz) breakdown tests were performed at room temperature (18 °C) using planar disc specimens and hemispherically-ended brass contact electrodes. The breakdown process caused the formation of a breakdown channel which terminated at the specimen surface in a crater. The breakdown strength was independent of the rate of voltage rise, but decreased exponentially (60 to 10 kV mm−1) with increasing specimen thickness. A high crystallinity content, good surface finish and a homogeneous microstructure yielded high breakdown strengths whilst poor microstructural development caused a reduction in breakdown strength. The breakdown mechanism is believed to be a combination of electronic, thermal and electromechanical processes.