A charge exchange model of sequential fragmentation applied to dissociative double ionization of hydrazoic acid and halogen azides
A charge exchange model of sequential fragmentation applied to dissociative double ionization of hydrazoic acid and halogen azides
复制标题
连续碎裂的电荷交换模型应用于叠氮酸和卤素叠氮化物的解离双电离
DOI：
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发表时间：
1995
期刊：
影响因子：
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通讯作者：
J. Eland
中科院分区：
文献类型：
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作者：
S. Hsieh;J. Eland
电荷分离反应模型包括碎片之间的电荷交换，包括顺序反应。该模型使用已知的分子结构，假设指数分布的中间寿命，并需要一个平均寿命作为唯一的一次性参数。的相对强度，峰宽，峰形的一般预测和定量计算示出同意与光电子-光离子-光离子符合光谱的HN 3，ClN 3，和IN 3和其他小分子的研究。
A model of charge separation reactions including charge exchange between fragments is developed to include sequential reactions. The model uses known molecular structures, assumes an exponential distribution of intermediate lifetimes, and requires a mean lifetime as the only disposable parameter. The general predictions and quantitative calculations of relative intensities, peak widths, and peak shapes are shown to agree with photoelectron–photoion–photoion coincidence spectra of HN3, ClN3, and IN3 and other small molecules studied previously.