A Novel Ferromagnetically Coupled Dinuclear Manganese(II) Complex with Phenoxo Bridges
A Novel Ferromagnetically Coupled Dinuclear Manganese(II) Complex with Phenoxo Bridges
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DOI：
10.1246/cl.2004.896
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发表时间：
2004-06
影响因子：
1.6
通讯作者：
S. Koizumi;M. Nihei;H. Oshio
中科院分区：
文献类型：
--
作者：
S. Koizumi;M. Nihei;H. Oshio
MnCl2.4H2O与四齿配体反应，生成双核锰配合物[MnII 2（H2 L）2 -Cl 2 ]（1）（H3 L = N-（2-羟基-5-硝基苄基）亚氨基二乙醇）.磁化率的测量表明，1具有S = 5自旋基态由于分子内的铁磁相互作用。
The reaction of MnCl 2 .4H 2 O with a tetradentate ligand yielded a dinuclear manganese(II) complex of [Mn I I 2 (H 2 L) 2 -Cl 2 ] (1) (H 3 L = N-(2-hydroxy-5-nitrobenzyl)iminodiethanol). The magnetic susceptibility measurement revealed that 1 has an S = 5 spin ground state due to an intramolecular ferromagnetic interaction.