High-yield reduction of carbon dioxide into formic acid by zero-valent metal/metal oxide redox cycles
High-yield reduction of carbon dioxide into formic acid by zero-valent metal/metal oxide redox cycles
复制标题
通过零价金属/金属氧化物氧化还原循环高产率地将二氧化碳还原为甲酸
DOI：
10.1039/c0ee00661k
复制
发表时间：
2011-03-01
影响因子：
32.5
通讯作者：
Smith, Richard L., Jr.
中科院分区：
文献类型：
--
作者：
Jin, Fangming;Gao, Ying;Smith, Richard L., Jr.
描述了一种减少CO2的策略，该策略从CO2产生甲酸（约100%）。80%甲酸产率）。氧化的金属可以使用甘油再生，甘油产生乳酸。氢的生产证明，通过金属氧化在CO2的存在下与零价铁，锰，锌，和铝金属在水热条件下，其中发现，最大的氢形成产率约。达到99.4%。金属一旦被氧化，就很容易被还原（约。Fe为100%）通过与甘油接触转变为零价态。结果表明，碳循环可以由常用金属的氧化和还原驱动。
A strategy for reduction of CO2 is described that produces formic acid from CO2 (ca. 80% formic acid yield) via the oxidation of a zero-valent metal under hydrothermal conditions. The oxidized metal can be regenerated using glycerin, which produces lactic acid. Hydrogen production is demonstrated through metal oxidation in the presence of CO2 with zero-valent Fe, Mn, Zn, and Al metals under hydrothermal conditions, where it is found that a maximum hydrogen formation yield of ca. 99.4% was achieved. The metals, once oxidized, could be readily reduced (ca. 100% for Fe) to their zero-valent state by contact with glycerin. The results demonstrate that a carbon cycle can be driven by the oxidation and reduction of commonly available metals.