Attempted Abstraction of the Halogenides in (HNEt3)Re(CH3CN)(2)Cl-4] and Crystal Structures of cis-Re(CH3CN)(2)Cl-4] center dot CH3CN and cis-Re(NHC(OCH3)CH3)(2)Cl-4]
Attempted Abstraction of the Halogenides in (HNEt3)Re(CH3CN)(2)Cl-4] and Crystal Structures of cis-Re(CH3CN)(2)Cl-4] center dot CH3CN and cis-Re(NHC(OCH3)CH3)(2)Cl-4]
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(HNEt3)Re(CH3CN)(2)Cl-4]中卤化物的尝试提取以及顺式-Re(CH3CN)(2)Cl-4]中心点CH3CN和顺式-Re(NHC(OCH3)CH3的晶体结构
DOI：
10.5167/uzh-65731
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发表时间：
2007
期刊：
影响因子：
--
通讯作者：
R. Alberto
中科院分区：
文献类型：
--
作者：
P. Kunz;Philipp Kurz;B. Spingler;R. Alberto
Re（CH_3CN）（2）Cl ~（4-）]（-）中的卤化物配体的夺取应产生仅溶剂稳定的Re-III络合物。本文研究了Re（CH_3CN）（2）Cl ~-4]（-）盐与银（1）和铊（I）盐的反应，并描述了cis-Re（CH_3CN）（2）Cl ~-4]中心点CH_3CN和cisRe（NHC（OCH_3）CH_3）（2）Cl ~-4]的固态结构。
The abstraction of the halogenide ligands in Re(CH3CN)(2)Cl-4](-) should result in a solvent-only stabilized Re-III complex. The reactions of salts of Re(CH3CN)(2)Cl-4](-) with silver(1) and thallium(I) salts were investigated and the solid-state structures of cis-Re(CH3CN)(2)Cl-4] center dot CH3CN and cisRe(NHC(OCH3)CH3)(2)Cl-4] are described.